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A single-step method for aniline formation was examined. Using a vanadate catalyst with an iron oxide co-catalyst and hydroxylamine hydrochloride as the amine source, an up to 90% yield of aniline was obtained with high selectivity. Further study showed that the overall reaction was pseudo-second order in terms of hydroxylamine concentration. Regioselective H-D exchange experiments suggest that the C-N bond formation step occurs via an irreversible electrophilic pathway. Based on all of the key observations, a mechanism is proposed. 

The Long Wavelength Array is a radio telescope array located at the Sevilleta National Wildlife Refuge in La Joya, New Mexico, well suited and situated for the observation of lightning. The array consists of 256 high-sensitivity dual polarization antennas arranged in a 100 m diameter. This paper demonstrates some of the capabilities that the array brings to the study of lightning. Once 32 or more antennas are used to image lightning radio sources, virtually every integration period longer than the impulse response of the array includes at least one identifiable lightning emitter, independent of the integration period used. The use of many antennas also allows multiple simultaneous lightning radio sources to be imaged at sub-microsecond timescales; for the flash examined, 51% of the images contained more than one lightning source. Finally, by using many antennas to image lightning sources, the array is capable of locating sources fainter than the galactic background radio noise level, yielding possibly the most sensitive radio maps of lightning to date. This incredible sensitivity enables, for the first time, the emissions originating from the positive leader tips of natural in-cloud lightning to be detected and located. The tip emission is distinctly different from needle emission and is most likely due to positive breakdown. 

Three-dimensional radio and optical mapping reveals that streamers of jets can extend from cloud top to the ionosphere. 

We propose that the upcoming Decadal Survey on Solar and Space Physics describe prominent contributions of lightning and its impacts beyond the troposphere, particularly within the NASA Heliophysics portfolio. We present a brief review of several topics highly relevant to NSF and NASA. We opt to unify these topics into one white paper, with longer reviews/references included. 

Abstract Electric fields associated with a developing natural lightning leader are difficult to measure. This work demonstrates a new approach to indirectly probing the electric fields in the streamer zone of a lightning leader. Using a 10–250 MHz broadband lightning interferometer, very high frequency (VHF) radio emissions from the tip of a positive cloud‐to‐ground (CG) leader were measured and localized. We specially use a normalized spectral analysis to avoid the challenge of absolute system calibration to show that the positive leader spectrum exhibits a clear cutoff frequency at 80 MHz. Compared with theoretical predictions, this cutoff frequency corresponds to a streamer growth rate ofand an average electric field of 0.9 times the conventional breakdown fieldin streamer bursts from the positive leader. Implications for the detectability of positive leaders through VHF emissions and for the production of X‐rays by positive leaders are analyzed. 

Abstract This paper reports a study to understand the radio spectrum of thunderstorm narrow bipolar events (NBEs) or compact intracloud discharges, which are powerful sources of high‐frequency (HF) and very high frequency (VHF) electromagnetic radiation. The radio spectra from 10 kHz to about 100 MHz are obtained for three NBEs, including one caused by fast positive breakdown and two by fast negative breakdown. The results indicate that the two polarities of fast breakdown have similar spectra, with a relatively flat spectrum in the HF and VHF band. The ratio of energy spectral densities in the very low frequency and HF bands is (0.9–5) × 10⁵. We develop a statistical modeling approach to investigate if a system of streamers can explain the main features of fast breakdown. Assuming that the current moment peak and charge moment change of individual streamers vary in the ranges of 5–10 A‐m and 5–20 μC‐m, respectively, the modeling results indicate that a system of 10⁷–10⁸streamers can reproduce the current moment, charge transfer, and radio spectrum of fast breakdown. The rapid current variation on a time scale of nanoseconds required for fast breakdown to produce strong HF/VHF emissions is provided by exponentially accelerating and expanding streamers. Our study therefore supports the hypothesis that fast breakdown is a system of streamers. Finally, suggestions are given regarding future streamer simulations and NBE measurements in order to further develop our understanding of NBEs and lightning initiation.